However, the tell-tale sign of a molybdenum deficiency is the leaves may start to display a unique orange, red or pink color around the edges which will start to move toward the center of the leaf. Molybdenum is an essential trace mineral that helps the body to break down proteins and certain toxic substances including alcohol. However, the crops previously listed will often respond to Molybdenum applications where the soil pH is below 6.2. Most soil analytic techniques lack well calibrated interpretive methodology (the correlation between extractable Mo and crop response is the weakest of all the essential nutrients). Heavy metals (HMs) exists in the environment in both forms as essential and non-essential. Molybdenum deficiency is very rare; the vast majority of people get enough molybdenum from their diet. Some experts, therefore, believe it plays a major role in detoxification processes. Abbreviations AO aldehyde … As rare as molybdenum deficiency is in cannabis plants, toxicity is even less so. The main symptoms of molybdenum deficiency in non-legumes are stunting and failure of leaves to develop a healthy dark green colour. The symptoms associated with deficiency of Mo are closely related to nitrogen (N) metabolism. Both defects are autosomal recessive traits. Molybdenum is an essential component of two major enzymes in plants, nitrogenase and nitrate reductase. In non-legumes (such as cauliflowers, tomatoes, lettuce, sunflowers and maize), molybdenum enables the plant to use the nitrates taken up from the soil. It is essential to the conversion of inorganic P into organic forms in the plant. Functions of Nitrogen in Plants: Comprises all amino acids. Nitrate reductase is the most well-studied molybdenum-containing enzyme. In advanced stages, the leaf tissue at … Copper 5. Molybdenum toxicity may interfere with copper absorption and cause gout-like symptoms. Moco is particularly involved in enzymes, which participate directly or indirectly with nitrogen metabolism. Gout-Like Symptoms. Necrosis (dead tissue) on the margins and interveinal areas of older leaves may bear some resemblance to salinity damage or boron toxicity. Excess levels in plants are more of a concern to animal life, especially ruminants. Although higher plants require the balance of these essential elements by uptake from the soil, absorption of a higher Mo amount may impose toxicity symptoms, and at the same time also induce antioxidant enzyme activity and increase of anthocyanin accumulation in plant tissues to overcome the excess metal stress (Stroud et al., 2010). Oxford University Press is a department of the University of Oxford. Smith FW, Hawkesford MJ, Ealing PM, Clarkson DT, Vanden Berg PJ, Belcher AR, et al. Much more research is required to ascertain the simple processes involved in how plants gain access to molybdenum and how the element may be used in the future to expand growing areas where soil molybdate profiles limit plant growth. The deficiency is called “whiptail” due to the whiplike appearance of leaves in Mo-deficient plants. The requirement of molybdenum in terms … Symptoms include severe brain damage, resulting in death at an early age. Broadcast applications for transplants are effective only where the soil pH is above 5.6. Colder weather can contribute to lacking molybdenum. Excess levels of a nutrient in the soil may lead to nutrient toxicity within a plant. Most analytic laboratories presently, do not offer soil analysis for Molybdenum on a routine basis. However, foliar application is favored for transplants. For the remaining two groups there is less information on their functionality in plants. As the deficiency gets worse necrosis begins in the smaller veins of the leaves but the main veins remain green, just like recovering iron deficient plants. Yellowish-re colored yound g leave Figurs 2. Molybdenum Deficiency Symptoms and Levels in Plants Molybdenum deficienc in foragy e legumes appears as a general yellowing of the whole plant an associated is witdh Figure 1. Yellow or reddish coloured leaves, stunted growth and poor flowering are all common symptoms of nitrogen, magnesium or potassium deficiency. Generally speaking values of over 1.0 ppm are considered adequate. Plant availability of Mn depends on soil adsorption and on root exudates for Mn chelation or reduction. Sometimes though, our plants don't grow as well as we would like. res.). Molybdenum: Deficiency & Toxicity Symptoms Next Lesson Manganese: Deficiency & Toxicity Symptoms Chapter 8 / Lesson 13 Transcript Colder weather can contribute to lacking molybdenum. In heifers, fertility is reduced. Those with molybdenum cofactor deficiency are deficient in all three molybdoenzymes due to lack of functional molybdopterin. Boron 7. It might inhibit plant growth by causing an oxidative damage to cells and interfering with the photosynthesis process. For full access to this pdf, sign in to an existing account, or purchase an annual subscription. When in excess, copper may also replace the magnesium (Mg 2+) in the chlorophyll molecule and impair the photosynthesis process. Plants are susceptible to such localized calcium deficiencies in low or non-transpiring tissues because calcium is not transported in the phloem. The leaves of affected plants show a pale green or yellowish green colour between the veins and along the edges. Excessive levels of heavy metals, such as copper, molybdenum, selenium, and zinc, in plant tissues can lead to stress conditions by inducing the … While this is an essential element for all plants, these crops have been found to be especially responsive. Molybdenum toxicity symptoms are brilliant golden yellow or blue tints, Reddish or golden yellow tints appear on shoots of potato and tomato while blue tints appear on shoots of barley and maize. Symptoms / Problems Guide; Grow Supplies; Fix a Molybdenum Deficiency in your Cannabis Plants. For Permissions, please email: journals.permissions@oxfordjournals.org, Slippery flowers as a mechanism of defence against nectar-thieving ants, The rachis cannot hold, plants fall apart. Mo: Molybdenum: Deficiency: Often interveinal chlorosis which occurs first on older leaves, then progressing to the entire plant. “This cucurbit plant is exhibiting molybdenum deficiency on the old leaves as overall yellowing, leaf margin necrosis and some interveinal chlorosis. For instance the mechanism controlling molybdenum transport to nitrogen fixing bacteroids may be a unique control mechanism by which the plant can regulate the symbiosis indirectly through molybdenum availability to support nitrogenase activity. Plant analyses are a better choice. PRIMARY MACRO-NUTRIENTS NITROGEN. If molybdenum toxicity exists then increasing the intake of copper can prevent it by binding the molybdenum in the gut and thus preventing it getting into the body. But, because of limited research the "sufficiency range" in plants is quite broad and not very well defined. Molybdenum nutrition is an essential component to healthy plant growth. Published by Oxford University Press on behalf of the Annals of Botany Company. Molybdenum - Role of Nutrient. However, in rats and mice molybdenum adversely affected reproduction and foetal development. Such symptoms would include a general pale greencolour, stunted growth with small leaf size, and possible reddening of veins onthe young leaves. Some common fertilizer products containing molybdenum include: It is essential to the symbiotic nitrogen fixing bacteria in legumes. Symptoms were tachycardia, tachypnea, headache, nausea, vomiting, and coma. Molybdenum transport in plants A thesis submitted for the Degree of the Doctor of Philosophy at The University of Adelaide Discipline of Wine and Horticulture, Molybdenum Deficiency Symptoms and Levels in Plants Molybdenum deficienc in foragy e legumes appears as a general yellowing of the whole plant an associated is witdh Figure 1. A commentary on: ‘The unique disarticulation layer formed in the rachis of, Field guide to the (wetter) Zambian miombo woodland, AVAILABILITY OF MOLYBDENUM IN AGRICULTURAL SOILS, IDENTIFICATION OF MOLYBDENUM AS AN ESSENTIAL PLANT ELEMENT, VISUAL SYMPTOMS OF MOLYBDENUM DEFICIENCY IN PLANTS, BIOCHEMICAL RESPONSE IN PLANTS TO MOLYBDENUM DEFICIENCIES, Receive exclusive offers and updates from Oxford Academic, Copyright © 2021 Annals of Botany Company. Nutrient Toxicity. VISUAL SYMPTOMS. Marginal leaf scorch and abscission as found in typical salt damage. In plants grown in solution culture, thefollowing symptoms were associated with a mild growth reduction from molybdenumdeficiency. Molybdenum is an exception in that it is readily translocated, and its deficiency symptoms generally appear on the whole plant. Based on the only documented … Although significant headway has been made in identifying genes encoding sulfate transport proteins very little information exists on the functional properties of most of these transporters in relation to anion selectivity, pH regulation and kinetic activities. Early studies in yeast demonstrated selenate and chromate as effective inhibitors of sulfate uptake (Breton and Surdin-Kerjan, 1977). Hesberg C, Haensch R, Mendel RR, Bittner F. Heuwinkel H, Kirkby EA, Le Bot J, Marschner H. Jones RW, Abbott AJ, Hewitt EJ, James DM, Best GR. Other symptoms include whiptail of leaves and distorted curding in cauliflower and destruction of embryonic tissue in some legumes. However, sheep and cattle feeding on plants with a high Mo concentration may suffer from molybdenosis. These spots begin to develop from the apex and then spread towards their base. Unkles SE, Wang R, Wang Y, Glass ADM, Crawford NM, Kinghorn JR. Vidmar JJ, Schjoerring JK, Touraine B, Glass ADM. Vieira RF, Cardoso EJBN, Vieira C, Cassini STA. However, copper is a poison, so if you are going to feed more copper you should only do so once you have calculated exactly how much copper you are feeding your cows. Tiny brown spots appear on lower leaves of paddy plant. These HM ions enter in soil biota from various sources like natural and anthropogenic. Search for other works by this author on: \(\mathrm{MoO}^{{-}}_{4}\ {>}\ \mathrm{HMO}_{4}^{{-}}\ {>}\ \mathrm{H}_{2}\mathrm{MO}_{4}^{0}\ {>}\ \mathrm{MoO}_{2}\left(\mathrm{OH}\right)^{+}\ {>}\ \mathrm{MoO}_{2}^{2+}\), Journal of the Australian Institute of Agricultural Science, Journal of the Council for Scientific and Industrial Research, Australian Journal of Scientific Research, Australian Journal of Agricultural Research, Soil Science Society of America Proceedings, New Zealand Journal of Science and Technology, The Australian Grapegrower and Winemaker. From our recent work with the grapevine cv. Photo 1. Studies on rats show a median lethal dose (LD 50) as low as 180 mg/kg for some Mo compounds. Using a selenate-resistant mutant YSD1, the selectivity of this mutant for sulfate transport and other anions such as molybdate is being explored. Sometimes this will cause symptoms of toxicity and sometimes it will prevent a plant from being able to uptake enough of one or more other nutrients and thus will lead to symptoms of nutrient deficiency. Too much copper will cause copper toxicity. Aluminum 3. Se and Mo foliar application could reduce the toxic symptoms in pollen grains when the one or the other was sprayed alone on plants. Group III transporters are mainly expressed in leaf tissues and account for five of the 14 sulfate-like transporters identified in arabidopsis. Agarwala SC, Sharma CP, Farooq S, Chatterjee C. Agarwala SC, Chatterjee C, Sharma PN, Sharma CP, Nautiyal N. Bolchi A, Petrucco S, Tenca PL, Foroni C, Ottonello S. Cherest H, Davidian J, Thomas D, Benes V, Ansorge W, Surdin-Kerjan Y. Fido RJ, Gundry CS, Hewitt EJ, Notton BA. Smith KS, Balistrieri LS, Smith SS, Severson RC. 1. main symptom of molybdenum is an upward cupping of the leaves and necrotic spots will appear if the deficiency reaches terminal status. (Usually Cu). Molybdenum toxicity is even less common than deficiency. Molybdenum is vital for the process of symbiotic nitrogen (N) fixation by Rhizobia bacteria in legume root modules. Much like with the more common nitrogen deficiency, molybdenum deficiency will first cause certain leaves of a cannabis plant to turn progressively more yellow. Walkenhorst HM, Hemschemeier SK, Eichenlaub R. Yaneva IA, Baydanova VD, Vunkova-Radeva RV. Symptoms pale leaves with interveinal and marginal chlorosis (yellowing) and necrosis (scald); the whiptail disorder in Brassica crops (especially cauliflower); decreased tasselling in maize; premature germination of maize grain. Manganese (Mn) toxicity in plants is often not a clearly identifiable disorder. The serious symptoms are due to lack of functional sulfite oxidase. Marginal leaf scorch and abscission as found in typical salt damage. Over-consumption of plant tissue high in Molybdenum can lead to a condition called Molybdenosis. Plant B concentrations of 20 to 50 ppm are considered to be optimum for the growth of forage legumes. Toxicity Symptoms. Four plant species (oilseed rape, Brassica napus L.; red clover, Trifolium pratense L.; ryegrass, Lolium perenne L.; and tomato, Lycopersicon esculentum L.) were tested on ten soils varying widely in soil properties to assess molybdenum (Mo) toxicity. Adequate Molybdenum minimizes the presence of nitrites and nitrates in plant tissues. In the absence of enough of the mineral, leaves turn pale and eventually die, flowers fail to form and some plant species experience malformed leaf blades in a condition called whiptail.Legumes fail to acquire the bacteria necessary to fix nitrogen to their root nodes. Smith FW, Ealing PM, Hawkesford MJ, Clarkson DT. Necrosis of cell tissue and poorly functioning vascular systems also cause general decay of plant health. Molybdenum competes with phosphorus utilization, resulting in reduced mineralization of bone. By removing molybdate from the media by activated charcoal scrubbing it has been possible to demonstrate that molybdate uptake at low external concentrations is also impaired in the yeast mutant (K. Gridley, unpubl. Where the plant has insufficient molybdenum the nitrates accumulate in the leaves and the plant cannot use them to make proteins. A plant’s sufficiency range is defined as the range of nutrient necessary to meet the plant’s nutritional needs and maximize growth (Figure 1). Manganese 4. Molybdenum (Mo) Chloride (Cl-) Silicon (Si) In the following, we will explore each of these key nutrients, their role/function within the plant and learn how to discern symptoms of toxicity and deficiency, as well as options for rectification. 2 mm) based on their functional properties when expressed in yeast cells. In general they reflect the way the plant responds to high internal manganese concentrations. Thus, selenate has been an effective screening tool to identify mutants that have disruptions in sulfate transport (Smith et al., 1995; Cherest et al., 1997). Even as a trace mineral, molybdenum for plant growth is an essential element. Because Mo is needed for nitrogenase activity, Mo … Molybdate which is the predominant form available to plants is required at very low levels where it is known to participate in various redox reactions in plants as part of the pterin complex Moco. The more capable labs may offer it as a special request. Sometimes the color appears in the middle of the leaves as … Because Mo is needed for nitrogenase activity, Mo deficiency … It usually starts off with yellowing of the older leaves and also yellowing between the veins. High molybdenum intake has also been linked to a number of other conditions. Doctors soon realized these symptoms were linked to a lack of molybdenum in the patient’s IV nutrition . All rights reserved. Toxicity Molybdenum toxicity is very rare and in some crops, the tissue can have several thousand ppm and still not show symptoms. The symptoms of manganese toxicity vary widely between plant species. Neubauer H, Pantel I, Lindgreen PE, Gotz F. Riley MM, Robson AD, Gartrell JW, Jeffery RC. It is found in the enzymes nitrate-reductase and nitrogenase which are essential for nitrate reduction and symbiotic Nfixation in plants. At high concentrations, molybdenum has a very distinctive toxicity symptom in that the leaves turn a very brilliant orange. Mo: Molybdenum: Deficiency: Often interveinal chlorosis which occurs first on older leaves, then progressing to the entire plant. by Parker Lewis. The form in which molybdenum is translocated is unknown. This condition is a result of high Mo concentrations suppressing the availability of dietary copper (Cu) in these animals. Gout is an inflammation of the joints due to accumulation of uric acid. Molybdenum is an essential mineral in the body, just like iron and magnesium. Gout-like symptoms have also been reported in an Armenian population consuming 10 to 15 milligrams (mg) of molybdenum from food daily . This low molybdate media screen has been incorporated into ongoing experiments where selected plant sulfate transporters are being expressed in yeast and ranked on their ability to rescue growth on reduced molybdenum concentrations. Merlot, we are starting to appreciate the influence of molybdenum on plant development and better understand mechanisms, which may be responsible for molybdenum uptake from the soil. In cultivar Wanmun, older leaves developed silvery patches overinterveinal tiss… It can be relaxing and you get to produce lovely flowers and tasty food. When you notice pink or reddish, orange color on the leaves of your cannabis plants this can be a sign of a molybdenum deficiency. Yellowish-re colored yound g leave Figurs 2. Some of them are. These changes lead to deformation of bones and joints, spontaneous pathological fractures of long bone metaphyses, and exostosis. Symptoms of Mn toxicity as well as the concentration of Mn that causes toxicity vary widely among plant species and varieties within species, perhaps because the phytotoxic mechanisms of Mn involve different biochemical pathways in different plant genotypes. Yellow or reddish coloured leaves, stunted growth and poor flowering are all common symptoms of nitrogen, magnesium or potassium deficiency. Zinc 6. In ornamental potted plants, Mo deficiency is not common, except for poin- ... vent some of the toxicity symptoms in some plants. Over-consumption of plant tissue high in Molybdenum can lead to a condition called Molybdenosis. VISUAL SYMPTOMS N utrient disorders may appear in many ways in a plant, including stunting or reduced growth, off-colored leaves (often white, yellow or purple); abno It is ironic that it took a new industry to be expanded in South Australia where molybdenum first made its mark as an essential plant element to again reinforce the importance of molybdenum in plant development. Maupin-Furlow JA, Rosentel JK, Lee JH, Deppenmeier U, Gunsalus RP, Shanmugam KT. Molybdenum deficiency may induce symptoms similar to those of nitrogen deficiency, as molybdenum is required for the assimilation of nitrate taken up by the plant. This element is essential but extremely toxic in excess. May vary depending on plant species. Molybdenum toxicity in plants is rare under most agricultural conditions. Laboratory tests showed high levels of sulfite and xanthine … Molybdenum Mo 0.0001 Involved in N fixation Nickel Ni 0.001 Component of enzymes Zinc Zn 0.03 Activates enzymes *Relative amounts of mineral elements compared to nitrogen in dry shoot tissue. Molybdenum is considered to be quite mobile as it moves readily in both the xylem and phloem conductive tissue of the plant. Still its highest concentration is in mature leaves because it binds readily with sulfur-containing amino-groups, sugars, and polyhydroxides which are usually in greater concentration in these leaves. Toxicity: Reduced growth followed by symptoms of iron chlorosis, stunting, reduced branching, abnormal darkening and thickening of roots. The result is that … Health Effects. There is an obvious requirement for more research into identifying the in planta function of the remaining sulfate transporters in plants before any of them can be nominated as putative molybdate permeases. Rare Deficiency Considering Mo’s importance in optimizing plant growth, it’s fortunate that Mo deficiencies are relatively rare in most agricultural cropping areas. Sanchez-Fernandez R, Emyr Davies TG, Coleman JOD, Rea PA. Schwacke R, Schneider A, van der Graaff E, Fischer K, Catoni E, Desimone M, et al. Molybdenum (Mo) Chloride (Cl-) Silicon (Si) In the following, we will explore each of these key nutrients, their role/function within the plant and learn how to discern symptoms of toxicity and deficiency, as well as options for rectification. Luque F, Mitchenall LA, Chapman M, Christine R, Pau RN. Grunden AM, Ray RM, Rosentel JK, Healy FG, Shanmugam KT. Alfalfa, broccoli, brussel sprouts, cabbage, cauliflower, clover, lettuce, peas, soybeans, spinach, sugarbeets, tomatoes, tobacco and most legumes. Molybdenum (Mo) deficient poinsettias exhibit halo-like marginal leaf chlorosis (yellowing) on recently matured leaves, leaf distortion or rolling and leaf edge burn. absorption of a higher Mo amount may impose toxicity symptoms, and at the same time also induce antioxidant enzyme activity and increase of anthocyanin accumulation in plant tissues to overcome the excess metal stress (Stroud et al., 2010). SynopsisBasic information about molybdenum as a plant nutrient, KeywordsMomolybdenummolymolybdatemicronutrientminor element, Molybdenum is essential for many plant functions. Stout PR, Meagher WR, Pearson GA, Johnson CM. For this reason, regular applications of Mo are not recommended for pastures. Schwartz SS, Leon-Kloosterziel KM, Koorneef M, Zeevart JAD. Recently, the arabidopsis AtSultr1;2, which is a member of the group I sulfate transporters, was shown to be involved in sulfate uptake in planta where a T-DNA lesion in the AtSultr1;2 locus allowed plants to grow on toxic concentrations of selenate and reduced its ability to accumulate sulphate into root tissues. In this article, the recent available information on W toxicity in plants and plant cells is reviewed, and the knowledge gaps and the most pertinent research directions are outlined. Plants absorb molybdenum as molybdate. Foliar deficiency symptoms are somewhat rare and positive responses may occur where there are no visible symptoms. Although copper is an essential micronutrient, excess of copper might be toxic to plants. Once molybdenum deficiency has been diagnosed, it should normally be fairly easy to address via either adjustment of growing medium pH or supplementation. Boro toxicitne symptomy ins alfalf a indicate B deficiency in alfalfa. The most common visible symptom is a pale yellowing resembling nitrogen deficiency. 10 to 20 ppm or more of molybdenum (MO) exhibit typical symptoms of MO toxicity (MO-induced Cu deficiency) and they respond to copper (Cu) supplement at ion. Molybdenum - Deficiency Symptons. Symptoms of Mn toxicity as well as the concentration of Mn that causes toxicity vary widely among plant species and varieties within species, perhaps because the phytotoxic mechanisms of Mn involve different biochemical pathways in different plant genotypes. However, Moco is also uniquely involved in ABA synthesis where it has a significant effect on ABA levels in plant cells and consequently a role in water relations and transpiration rates through stomatal control and in stress related responses. Faded hair coats, characteristic of Cu deficiency, and profuse diarrhea with foul, smelly feces are common symptoms of molybdenosis (Underwood, 1971). In contrast, molybdenum toxicity in plants under most agricultural conditions is rare. If plants fail to thrive, despite adequate soil preparation, watering and mulching, it may be a sign of a nutrient deficiency. In ornamental potted plants, Mo deficiency is not common, except for poin-settia. Yellowing or browning of leaves and depressed tillering. Molybdenum transport in plants A thesis submitted for the Degree of the Doctor of Philosophy at The University of Adelaide Discipline of Wine and Horticulture, These levels may differ by a factor of up to 10 4 (e.g., 0.1 to 1000 ppm dry weight). Cattle grazed on forage plants with 10 to 20 ppm or more of molybdenum (MO) exhibit typical symptoms of MO toxicity (MO-induced Cu deficiency) and they respond to copper (Cu) supplement at ion. It furthers the University's objective of excellence in research, scholarship, and education by publishing worldwide, This PDF is available to Subscribers Only. Molybdenum deficiency symptoms first appear be-tween the old and new leaves. PRIMARY MACRO-NUTRIENTS NITROGEN. Yellowing or browning of leaves and depressed tillering. Ammonium fertilizers tend to make the soil more acidic, and nitrate fertilizers tend to make the soil more alka-line. The symptoms associated with deficiency of Mo are closely related to nitrogen (N) metabolism. Molybdenum is needed by plants for chemical changes associated with nitrogen nutrition. Because the molybdenum content of plants depends on the soil molybdenum content and ... (an iron-oxidizing enzyme) have been reported in occupationally exposed workers in a molybdenite roasting plant . However, one avenue of research that could be explored further is the role of these transport proteins when expressed in heterologous expression systems such as yeast cells. Initial reports indicated a member of group IV (AtSultr4;1) may be targeted to chloroplasts (Shibagaki et al., 2002), while group V members are distantly related to members of group I–IV and no functional experimentation has been completed on them. Fruit and vegetables are particularly vulnerable, as are containerised plants and those growing in very acid or alkaline soils. Keywords: actin microfilaments, endoplasmic reticulum stress, unfolded protein response, microtubules, mitosis, molybdenum cofactor, programmed cell death, tungsten toxicity. Typical signs of acute, uncomplicated molybdenosis include impaired bone formation, which may be a result of altered phosphorus metabolism. This element is essential but extremely toxic in excess. Pica, unthriftiness, microcytic hypochromic anemia, emaciation, joint pain characterized by lameness, and osteoporosis often manifested by bone fractures are seen. Without molybdenum, plants may be able to take up inorganic phosphorus but they will struggle to convert that phosphorus into an organic form that they can use. and toxicity symptoms in plants can be difficult and plant analysis or soil testing Background Discussed in Nutrient Management Module 2, Plant Nutrition and Soil Fertility, plants require essential nutrients for normal functioning and growth. Excess levels in plants are more of a concern to animal life, especially ruminants. Abstract. appea on older leaves. Molybdenum is needed by plants for chemical changes associated with nitrogen nutrition. Other reported symptoms of molybdenum toxicity include [ 3, 9, 30 ]: Diarrhea Anemia Weight loss Loss of sexual desire After reading this article you will learn about the toxicity symptoms of various nutrients in plants:- 1. Molybdenum deficiency symptoms first appear be-tween the old and new leaves. There is also a large gap in the understanding of how molybdate enters plant cells and is redistributed between tissues of the plant. Shibagaki N, Rose A, McDermott JP, Fujiwara T, Hayashi H, Yoneyama T, et al. As stated earlier, be very careful with Molybdenum applications at pH's above 6.5, as yield reductions can occur. N/A. Involved in synthesis of ABA; Molybdenum - Nutrient in Soil. Discipline of Wine and Horticulture, School of Agriculture and Wine, University of Adelaide, PMB 1 Glen Osmond, South Australia 5064, Australia. 28th Annual Technical Issue, Proceedings of the National Academy of Sciences of the USA, Australian Journal of Biological Sciences, Biochemical and Biophysical Research Communications, Zeitschrift für Pflanzenernahrung und Bodenkunde, © The Author 2005.